Scheme overview
The Workplace Analysis Scheme for Proficiency (WASP) tests the
performance of laboratories measuring exposure to hazardous
substances in the workplace/ambient air such as lead, benzene
and respirable quartz. It was established in 1988 and is one
of the largest schemes of its kind with over 200 laboratories
participating worldwide. The WASP scheme is operated by HSL, which
oversees management, registration, and membership matters together
with distribution of the samples, processing the participant data
and providing performance reports.
The participant handbook can be found
here which provides a comprehensive overview of the
operation of the WASP PT scheme.
Analytes in the scheme
|
Analyte
|
Nominal Loading
Range
µg/sample
|
Medium
|
|
Inorganics at workplace air
concentrations
|
|
Lead
|
15 - 150
|
9 metals spiked onto a
membrane or glass fibre filter (25 mm diameter)
|
|
Cadmium
|
5 - 50
|
|
Chromium
|
50 - 500
|
| Cobalt, Copper, Iron, Manganese
Nickel and Zinc |
10 - 250 |
|
Cobalt, Copper, Chromium,
Nickel, Manganese, Zinc and Iron
|
1 - 30 % (m/m)*
|
~ 10 mg bulk welding fume
sample
|
|
Quartz
|
60 - 300
|
Respirable grade quartz aerosolised
and sampled onto PVC filters (GLA 5000 - 25 mm diameter)
mounted in Higgins Dewell cyclonic samplers. Resultant filters
supplied as test samples to participants.
|
| Gravimetric |
0.2 - 2 mg |
Glass fibre filters (25 or 37
mm diameter) spiked with sodium borate and dried to simulate dust
(mass) deposit. |
|
Inorganics at ambient air concentrations
|
| Nitrogen dioxide (as
nitrite) |
0.3 - 2 |
Spiked onto triethaolamine
(TEA) coated grids mounted in Palmes type diffusive air
samplers |
* indicative concentrations, balance Iron. Samples may contain
some or all of the stated elements. Welding fume samples supplied
upon request to participants subscribing to spiked metal filter
sample.
|
Analyte
|
Nominal Loading
Range
µg/sorbent
tube
|
Medium
|
|
Organics at workplace air
concentrations - Solvent Desorption
|
|
Benzene
|
10 - 400
|
4 substances provided together on
a glass sorbent tube packed with charcoal. Test samples
dynamically loaded from a standard atmosphere.
(also available for thermal
desorption - see below)
|
|
Toluene
|
50 - 2500
|
|
Xylene (all isomers)
|
50 - 5000
|
|
Ethyl Benzene
|
20 - 400
|
|
1,1,1-Trichloroethane
|
250 - 12000
|
3 substances provided together on
a glass sorbent tube packed with charcoal. Test samples
dynamically loaded from a standard atmosphere.
|
|
Trichloroethene
|
80 - 7000
|
|
Tetrachloroethene
|
100 - 4000
|
|
Formaldehyde
|
3 - 60
|
Spiked Glass fibre filter with
2,4,DNPH derivative
|
|
Analyte
|
Nominal Loading
Range
µg/sorbent
tube
|
Medium
|
| Organics at workplace air
concentrations - Thermal Desorption |
|
Benzene
|
0.5 - 15
|
4 substances provided together on
a Perkin Elmer type TD sorbent tube* packed with Tenax TA.
Test samples dynamically loaded from a standard atmosphere.
|
|
Toluene
|
2 - 200
|
|
Total xylene (all isomers)
|
2 - 200
|
|
Ethyl Benzene
|
0.5 - 50
|
|
Analyte
|
Nominal Loading
Range
ng/sorbent
tube
|
Medium
|
| Organics at ambient air
concentrations - Thermal Desorption |
|
Benzene
|
15 - 300
|
4 substances provided together on
a Perkin Elmer type TD sorbent tube* packed with Tenax TA.
Test samples dynamically loaded from a standard atmosphere.
|
|
Toluene
|
15 - 300
|
|
Total xylene (all isomers)
|
15 - 300
|
|
Ethyl Benzene
|
15 - 300
|
* It may be possible to accommodate alternative sorbent tube
designs, please contact HSL.
Who should participate?
Laboratories undertaking analysis of workplace and ambient air
samples. The scheme is open to worldwide
participants.
Laboratories accredited to the American Industrial Hygiene
Association (AIHA) wishing to join the WASP PT scheme are requested
to join via the AIHA proficiency
testing program. Please note that WASP round reports for
these participants are supplied to AIHA IHPAT scheme
organisers.
What analytical methods should be used?
Participants are free to use whatever methods are deemed
appropriate. Analytical methods developed by HSL and
published in the HSE Methods for the Determination of Hazardous
Substances can be downloaded here.
A useful method information source is the
GESTIS database. This database contains a list of
validated analytical procedures described as suitable for the
analysis of chemical agents at workplaces and draws upon methods
developed both at an international (ISO) and at a national
level (e.g. methods developed in . France (INRS), Germany
(IFA), UK (HSL) and the USA (NIOSH/OSHA) ).
Analytical guidance for the analysis of palmes type diffusion
tube used in the WASP NO2 PT scheme can be found
here on the UK Defra website.
Participants can also contact HSL for measurement advice
through the PT Team..
Operation of the scheme
The samples are prepared on various sampling media dependent on
the analyte (see tables above).
Four test samples (plus associated blank samples) are sent to
participants every three months for each of the analyte categories.
Laboratories typically have one month to analyse the samples and
report the results. The gravimetric and silica test
samples are supplied on a two round per annum basis. Two welding
fume test samples are supplied once a year.
The WASP gravimetric scheme has an additional step. Initially
blank filters are dispatched to participants in order for them to
weigh. Participants then ship the filters back to HSL for spiking.
HSL resends the spiked filters back to the participants for
reweighing who then report the results (reweighing value - initial
blank value) to HSL for assessment.
Participants upon completion of the round receive a report
detailing their performance. Please note that WASP round reports
for participants joining via AIHA (see above) are also
supplied to the AIHA IHPAT scheme organisers.
Performance is classified as good, satisfactory or
unsatisfactory.
Scheme Schedule
|
Round Number
|
Samples Despatched
(Week Commencing)
|
Results
Deadline
|
Reports
Despatched
(Week
Commencing)
|
| 88 |
24 January
2011 |
11 March
2011 |
28 March
2011 |
| 89 |
2 May 2011 |
10 June 2011 |
27 June 2011 |
| 90 |
11 July 2011 |
2 September 2011 |
26 September 2011 |
| 91 |
17 October 2011 |
9 December 2011 |
2 January 2012 |
| 92 |
23 January 2012 |
9 March 2012 |
26 March 2012 |
Scheme Schedule (gravimetric analyte
only)
|
Round
Number
|
Filters Despatched
(Week Commencing)
|
Filters required back at
HSL by
|
Filters
Re-dispatched
(Week
Commencing)
|
Results
deadline |
Reports Despatched
(Week Commencing) |
| 12 |
3
January 2011 |
11
February 2011 |
28
February 2011 |
1 April 2011 |
16 May 2011
|
| 13 |
9 May 2011
|
17 June
2011 |
4 July 2011
|
12 August 2011
|
5 September 2011 |
| 14 |
3 October 2011 |
25 November 2011 |
2
January 2012 |
17 February 2012 |
5 March 2012 |
Scheme Schedule
(NO2 analyte only)
|
Round Number
|
Samples Despatched
(Week Commencing)
|
Results
Deadline
|
Reports Despatched (Week
Commencing)
|
|
112
|
17 January
2011 |
4 March
2011 |
28 March
2011 |
|
113
|
2 May 2011
|
10 June 2011
|
27 June 2011
|
|
114 |
11 July
2011 |
2
September 2011 |
26
September 2011 |
|
115 |
17
October 2011 |
9 December 2011 |
2 January 2011 |
| 116 |
23 January
2012 |
9 March 2012 |
26 March 2012 |
- Indicative dispatch dates. Participants will be notified by
email of any changes if dispatches do not occur within stated
week
- HSL currently uses Royal Mail Parcel Force to dispatch WASP
samples and reports to UK and EU participants. For non-EU
participants HSL employs a courier. The anticipated transit times
(if cleared by customs) are
- 2 - 4 working days for UK customers
- 2 - 5 working days for European customers
- 2 - 8 working days for RoW customers
- Customers should contact HSL if samples do not arrive within
the anticipated times
Round specific information and paperwork
Result form for WASP Gravimetric Round 14 can be found here.
Results form for WASP Round 92 (Solvents) can be found here.
Results form for WASP Round 92 (Formaldehyde, Quartz &
Metals) can be found here.
WASP training DVD
In order to provide technical guidance to laboratories, HSL has
produced a training DVD. This is based on the procedures in HSE's
series 'Methods for
the Determination of Hazardous Substances' and ISO
publications, and gives practical tips about how to achieve
accurate results.
It is assumed however that the viewer has some previous
knowledge of the techniques and analytical methods
descibed.
The topics covered include:
- The analysis of metals on filter analysis using inductively
coupled plasma - atomic absorption spectrometry (ICP-AES);
- The analysis of chemicals on charcoal by solvent desorption and
gas chromatography (GC) analysis;
- The analysis of chemicals on tenax for thermal desorption and
GC analysis;
- The analysis of isocyanate derivatives on glass fibre filters
using High Performance Liquid Chromatography (HPLC).
Download extract from
DVD
NB To view this extract you need Windows Media Player. To
download software please use the link below:
www.microsoft.com/windows/windowsmedia/download/default.asp
Contact information for further details
For further details or to join please email proficiency.testing@hsl.gov.uk
or contact:
The Proficiency Testing Team
Health and Safety Laboratory
Harpur Hill
Buxton
Derbyshire
SK17 9JN
Tel: 00 44 (0)1298 218553
Fax: 00 44 (0)1298 218572